Ni+–CO was generated by using a newly prepared square-planar nickel compound with an aliphatic thiolato–thioether sulfur ligand, with relevance to the nickel centre of carbon monoxide dehydrogenase.
T. Yamamura, S. Sakurai, H. Arai and H. Miyamae, J. Chem. Soc., Chem. Commun., 1993, 1656 DOI: 10.1039/C39930001656
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