Issue 21, 1993

Effect of water on the mechanism of hydrogenations catalysed by rhodium phosphine complexes

Abstract

On the action of H2 in aqueous solutions, the water soluble analogue of Wilkinson's catalyst, [RhCl(tppms)3][tppms[double bond, length as m-dash]P(C6H5)2(C6H4SO3Na)], gives [RhH(tppms)3] instead of [RhH2Cl(tppms)3] and this is reflected in the rates and selectivities of hydrogenations using this catalyst.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1602-1604

Effect of water on the mechanism of hydrogenations catalysed by rhodium phosphine complexes

F. Joó, P. Csiba and A. Bényei, J. Chem. Soc., Chem. Commun., 1993, 1602 DOI: 10.1039/C39930001602

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