(NEt4)3[V6O2S4(edt)6]·EtCN 2(edtH2= ethane-1,2-dithiol) has been obtained in small yield (5–10%) from (NEt4)Na[VS(edt)2]; complex 2 has a structure comprising two VO2+ units bound to a [V4S4] core and thus represents a model for the adsorption of [VO]2+ species on the surface of V sulfides during crude oil hydrotreating processes.
K. A. York, K. Folting and G. Christou, J. Chem. Soc., Chem. Commun., 1993, 1563 DOI: 10.1039/C39930001563
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