Detection of oxidation radicals of 2,3-enediol form of 2,3-dioxoguluno-δ-lactone by pulse radiolysis
Abstract
The OH adduct radicals of the 2,3-enediol form of 2,3-dioxoguluno-δ-lactone (2,3-End.DKGL) have been observed in aqueous solution by puise radiolysis (the adduct radicals were converted into the one-electron oxidation radical in alkaline solutions by dehydration); the oxidation radical has also been produced by oxidation of 2,3-End.DKGL by the azide radical (N3˙).