O-Glycosidations of glycals 1, 8 and 9 with several alcohols by using a catalytic amount of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) under neutral conditions proceeds smoothly to give the corresponding 2,3-unsaturated glycosides in high yields.
K. Toshima, T. Ishizuka, G. Matsuo, M. Nakata and M. Kinoshita, J. Chem. Soc., Chem. Commun., 1993, 704 DOI: 10.1039/C39930000704
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