The novel epoxidation of diadamantylidene 1 and related hindered olefins with NO2 proceeds by way of the cation radical 1+˙ generated during the electron-transfer chain (ETC) catalysis initiated by nitrosonium.
E. Bosch and J. K. Kochi, J. Chem. Soc., Chem. Commun., 1993, 667 DOI: 10.1039/C39930000667
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