Issue 7, 1993

Steric acceleration of intramolecular azide cycloadditions

Abstract

Use of conformational restraints, induced by different ortho-substituents in 1-allyloxy- and 1-prop-2-ynyloxy-2-azidomethylbenzenes, can be employed to enhance the smooth intramolecular addition of the azide group to the unsaturated bond, followed by, in one example, removal of the conformational constraint.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 607-608

Steric acceleration of intramolecular azide cycloadditions

B. S. Orlek, P. G. Sammes and D. J. Weller, J. Chem. Soc., Chem. Commun., 1993, 607 DOI: 10.1039/C39930000607

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