A stannaimine has been isolated for the first time; the tin atom is surrounded by three nitrogen atoms in a planar arrangement and the tin–nitrogen double bond is shortened by 10 pm compared with tin–nitrogen single bonds.
G. Ossig, A. Meller, S. Freitag and R. Herbst-Irmer, J. Chem. Soc., Chem. Commun., 1993, 497 DOI: 10.1039/C39930000497
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