Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl2(CNR)2](R = But,p-MeOC6H4) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBut)]2

Florence A. Ajulu; Peter B. Hitchcock; François Mathey; Rino A. Michelin; John F. Nixon; A. J. L. Pombeiro

doi:10.1039/C39930000142

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Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl₂(CNR)₂](R = Bu^t,p-MeOC₆H₄) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBu^t)]₂

Florence A. Ajulu, Peter B. Hitchcock, François Mathey, Rino A. Michelin, John F. Nixon and A. J. L. Pombeiro

Abstract

A new type of ligating behaviour of the phosphirene ring system [graphic omitted]Ph is described, in which novel dimeric platinum(II) Chlorophosphane complexes result from phosphirene ring opening and a Pt–Cl bond-insertion reaction.

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DOI: https://doi.org/10.1039/C39930000142
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1993, 142-143

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Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl₂(CNR)₂](R = Bu^t,p-MeOC₆H₄) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBu^t)]₂

F. A. Ajulu, P. B. Hitchcock, F. Mathey, R. A. Michelin, J. F. Nixon and A. J. L. Pombeiro, J. Chem. Soc., Chem. Commun., 1993, 142 DOI: 10.1039/C39930000142

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Journal of the Chemical Society, Chemical Communications

Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl₂(CNR)₂](R = Bu^t,p-MeOC₆H₄) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBu^t)]₂

Abstract

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Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl₂(CNR)₂](R = Bu^t,p-MeOC₆H₄) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBu^t)]₂

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