Issue 13, 1992

Easy access to a new class of anionic cyano-bridged di- and tri-nuclear organotin adducts. Crystal structure of [N(PPh3)2][ClPh3Sn(µ-NC)Ag(CN)]

Abstract

Cyanometallates [N(PPh3)2][Ag(CN)2]1 and [N(PPh3)2]2[Pd(CN)4]2 reacted with SnPh3Cl, producing anionic complexes characterized by IR and 119Sn NMR spectroscopy, an X-ray structural analysis of the silver complex evidencing a Sn–NC–Ag bridging interaction; the crystal structure of 1 has also been determined for comparison.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2127-2128

Easy access to a new class of anionic cyano-bridged di- and tri-nuclear organotin adducts. Crystal structure of [N(PPh3)2][ClPh3Sn(µ-NC)Ag(CN)]

M. Carcelli, C. Ferrari, C. Pelizzi, G. Pelizzi, G. Predieri and C. Solinas, J. Chem. Soc., Dalton Trans., 1992, 2127 DOI: 10.1039/DT9920002127

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