Proton sponge [1,8-bis(dimethylamino)naphthalene] acts as a carbon nucleophile towards co-ordinated alkenes in [Pt(η2-alkene)Cl(Me2NCH2CH2NMe2)]+(alkene = ethylene, propene or styrene), the resulting Pt–C σ bond being cleaved by acids to afford the 4-alkyl-substituted base.
L. Maresca, G. Natile and F. P. Fanizzi, J. Chem. Soc., Dalton Trans., 1992, 1867 DOI: 10.1039/DT9920001867
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