Issue 7, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Photo-oxidation of [Re2(CO)10] in low-temperature matrices containing O2

Matthew J. Almond  and  Rachel H. Orrin  

Abstract

Photo-oxidation of [Re2(CO)10] isolated in low-temperature matrices containing O2 generates, alongside free CO and CO2, the binary oxide Re2O7. The reaction appears to be initiated by Re–Re bond cleavage and proceeds via at least two detectable oxorhenium carbonyl species. Infrared spectroscopic studies, including isotopic substitution with 18O and 13C, suggest that these intermediates are most likely to be (OC)5Re–O–O–Re(CO)5 and O[double bond, length half m-dash]Re(CO)5.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9920001229
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 1229-1234

Permissions

Request permissions

Photo-oxidation of [Re2(CO)10] in low-temperature matrices containing O2

M. J. Almond and R. H. Orrin, J. Chem. Soc., Dalton Trans., 1992, 1229 DOI: 10.1039/DT9920001229

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements