We report the first direct observation of the push effect of the sixth ligand on the heterolytic O–O bond cleavage step of acylperoxo-iron(III) porphyrin complexes to the corresponding oxo-ferryl porphyrin π-cation radicals by utilizing a series of imidazole derivatives.
K. Yamaguchi, Y. Watanabe and I. Morishima, J. Chem. Soc., Chem. Commun., 1992, 1709 DOI: 10.1039/C39920001709
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...