The complex [RuCl{7,8-µ-S(CH2CH2)S-C2B9H10}(PPh3)2]·Me2CO 1 contains octahedral ruthenium(II), the sixth coordination site being occupied by an agostic B–H⇀Ru in the first example of B(3)–H⇀Ru coordination in the solid state; solution NMR studies show the presence of B(3)–Ru–H bonding.
F. Teixidor, J. A. Ayllón, C. Viñas, R. Kivekäs, R. Sillanpää and J. Casabó, J. Chem. Soc., Chem. Commun., 1992, 1281 DOI: 10.1039/C39920001281
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