Montmorillonite KSF at room temperature without solvent catalyses the synthesis of dithiolanes and dithianes from carbonyl compounds; chemoselectivity in dithiane and dithiolane formation is observed between aromatic aldehydes and ketones and between aromatic and aliphatic aldehydes.
D. Villemin, B. Labiad and M. Hammadi, J. Chem. Soc., Chem. Commun., 1992, 1192 DOI: 10.1039/C39920001192
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