Solid-state 13C CP MAS NMR studies of compounds [(Me3Sn)4M(CN)6]∞ with M = Fe, Ru and Os, using variable temperature, show that the trigonal bipyramidal arrangements at Sn are undergoing internal rotation about the N-Sn-N axes with lifetimes of the order of 0.5 s at moderately lowered temperature.
D. C. Apperley, N. A. Davies, R. K. Harris, S. Eller, P. Schwarz and R. D. Fischer, J. Chem. Soc., Chem. Commun., 1992, 740 DOI: 10.1039/C39920000740
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