The reaction of silver trifluoromethanesulfonate 2 with zinc bis[bis(trimethylsilyl)amide]4 and 2,4,6-triisopropylbenzenethiol 5 in a 4 : 4 : 6 ratio yields the mixed metal thiolate complex 3 with a twelve-membered silver–zinc–sulfur ring bridged by two trifluoromethanesulfonate anions; compound 3 is remarkably stable in solution.
M. Steiner, H. Grützmacher, L. Zolnai and G. Huttner, J. Chem. Soc., Chem. Commun., 1992, 689 DOI: 10.1039/C39920000689
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