Photoinduced intramolecular electron transfer in donor–acceptor systems separated by a long distance are studied by fluorescence quenching experiments; reduced rate constants for electron transfer are observed in highly exothermic reactions, which indicates the existence of an ‘inverted region’, in accord with Marcus' model.
S. Zhou, S. Shen, Q. Zhou and H. Xu, J. Chem. Soc., Chem. Commun., 1992, 669 DOI: 10.1039/C39920000669
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