Issue 9, 1992

Long distance intramolecular photoinduced electron transfer in donor–acceptor systems: effect of exothermicity on electron-transfer rates

Abstract

Photoinduced intramolecular electron transfer in donor–acceptor systems separated by a long distance are studied by fluorescence quenching experiments; reduced rate constants for electron transfer are observed in highly exothermic reactions, which indicates the existence of an ‘inverted region’, in accord with Marcus' model.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 669-670

Long distance intramolecular photoinduced electron transfer in donor–acceptor systems: effect of exothermicity on electron-transfer rates

S. Zhou, S. Shen, Q. Zhou and H. Xu, J. Chem. Soc., Chem. Commun., 1992, 669 DOI: 10.1039/C39920000669

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