Issue 8, 1992

Novel synthesis of a phosphinidene oxide-κP(RP[double bond, length half m-dash]O, R = ButCH2–) complex of rhenium(I) from a phosphaalkyne precursor. Crystal and molecular structure of [ReCl(Ph2PCH2CH2PPh2)2{P(O)CH2But}]

Abstract

The first example of the transformation of a phosphaalkyne to a phosphinidene oxide-κP ligand is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 645-646

Novel synthesis of a phosphinidene oxide-κP(RP[double bond, length half m-dash]O, R = ButCH2–) complex of rhenium(I) from a phosphaalkyne precursor. Crystal and molecular structure of [ReCl(Ph2PCH2CH2PPh2)2{P(O)CH2But}]

P. B. Hitchcock, J. A. Johnson, M. A. N. D. A. Lemos, M. F. Meidine, J. F. Nixon and A. J. L. Pombeiro, J. Chem. Soc., Chem. Commun., 1992, 645 DOI: 10.1039/C39920000645

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