A large intramolecular ferromagnetic interaction is observed in a titanium(IV) complex formed by two tridentate Schiff base semiquinoato radical ligands; this peculiar magnetic behaviour may be rationalised on the basis of the structural properties of the biradical compound.
A. Caneschi, A. Dei and D. Gatteschi, J. Chem. Soc., Chem. Commun., 1992, 630 DOI: 10.1039/C39920000630
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