NOESY has been used to demonstrate that, unexpectedly, [RuH2(CO)(PPh3)3] undergoes intramolecular ligand exchange, probably via the trigonal twist mechanism; it is shown how heteronuclear coupling in the NOESY experiment can yield valuable mechanistic information.
G. E. Ball and B. E. Mann, J. Chem. Soc., Chem. Commun., 1992, 561 DOI: 10.1039/C39920000561
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