Triarylbismuthines (Ar3Bi: Ar = C6H5, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4) react with atmospheric pressure of carbon monoxide in acetonitrile, tetrahydrofuran or methanol at 25 °C in the presence of a catalytic amount of either [RhCl(CO)2]2 or RhCl3·3H2O to produce the corresponding diaryl ketones in good yields, methyl benzoates being also formed in methanol.
C. S. Cho, T. Ohe, O. Itoh and S. Uemura, J. Chem. Soc., Chem. Commun., 1992, 453 DOI: 10.1039/C39920000453
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