Issue 2, 1992

A sulfur-assisted regioselective α-functionalization of cyclopropyl sulfides. Synthetic applications of homoallyl anion synthon

Abstract

γ,δ-Unsaturated γ-sulfenyl or sulfinlalkylmercury chlorides 5 and 15, generated from the cyclopropyl sulfide 7 and mercury (II) trifluoroacetate, were demonstrated to be homoallyl anion synthons; these compounds recyclized into the α-functionalized cyclopropyl sulfide on reaction with several electrophiles.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 192-193

A sulfur-assisted regioselective α-functionalization of cyclopropyl sulfides. Synthetic applications of homoallyl anion synthon

Y. Takemoto, T. Ohra, Y. Yonetoku, T. Imanishi and C. Iwata, J. Chem. Soc., Chem. Commun., 1992, 192 DOI: 10.1039/C39920000192

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