Several binuclear iron (III) compounds with a µ-alkoxo or µ-oxo bridge react with the spin-trapping reagent DMPO to yield DMPO–OH; the mechanism of the formation of DMPO–OH in solution is discussed.
Y. Nishida, M. Nasu and T. Akamatsu, J. Chem. Soc., Chem. Commun., 1992, 93 DOI: 10.1039/C39920000093
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