In an undivided cell fitted with a sacrifical anode and a nickel cathode on which cadmium had been deposited, the electroreduction of aromatic halides affords a strong base which allows the effective synthesis of β-oxo nitriles or β-oxo esters from the coupling of active-hydrogen compounds with esters.
R. Barhdadi, J. Gal, M. Heintz and M. Troupel, J. Chem. Soc., Chem. Commun., 1992, 50 DOI: 10.1039/C39920000050
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