Issue 12, 1991

Arylation of heterocyclic ketene aminals with 2,4-dinitrohalobenzenes by a radical nucleophilic substitution mechanism

Abstract

The anions of heterocyclic ketene aminals reacted with 2,4-dinitrohalobenzenes to give arylated products by a radical nucleophilic substitution mechanism. The SRN1 mechanism was confirmed by EPR spectroscopy, EPR spin trapping, and by depression of the reaction rate by the addition of an inhibitor.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1991, 1967-1970

Arylation of heterocyclic ketene aminals with 2,4-dinitrohalobenzenes by a radical nucleophilic substitution mechanism

W. Zhao and Z. Huang, J. Chem. Soc., Perkin Trans. 2, 1991, 1967 DOI: 10.1039/P29910001967

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