Issue 5, 1991

Crystal structure and pressure dependence of electrical conductivities of [(CH3)4N][Pt(dmit)2]2

Abstract

The crystal structure and electrical conductivities (including the effect of pressure) of [(CH3)4N][Pt(dmit)2]2(dmit = 4,5-dimercapto-1,3-dithiole-2-thione) have been studied. The Pt(dmit)2 anions form dimeric structures arranged as one-dimensional stacks along the [110] and [1[1 with combining macron]0] directions. A simple band-energy calculation indicates that the conduction band is formed by the HOMO band of Pt(dmit)2 owing to the strong dimeric nature of the molecular stacks.

Article information

Article type
Paper

J. Mater. Chem., 1991,1, 827-830

Crystal structure and pressure dependence of electrical conductivities of [(CH3)4N][Pt(dmit)2]2

A. Kobayashi, A. Miyamoto, H. Kobayashi, A. Clark and A. E. Underhill, J. Mater. Chem., 1991, 1, 827 DOI: 10.1039/JM9910100827

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