Rate and thermodynamic parameters have been obtained for protonation reactions of the α-alanine zwitterion using modulated temperature and electrical conductivity measurements. In some of the reactions, the free-energy change is dominated by the entropy change.
M. A. Slifkin and S. M. Ali, J. Chem. Soc., Faraday Trans., 1991, 87, 3241 DOI: 10.1039/FT9918703241
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