A cationic acetylpalladium(II) complex cis-[Pd(COMe)(NCMe)(dppe)]+BF4–2 exhibits extremely high reactivity toward simple alkenes including cyclopentene, cycloheptene and methyl acrylate to give the corresponding alkene-inserted complexes, which have been characterised by IR and NMR spectroscopy.
F. Ozawa, T. Hayashi, H. Koide and A. Yamamoto, J. Chem. Soc., Chem. Commun., 1991, 1469 DOI: 10.1039/C39910001469
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