Issue 19, 1991

N-bonded TCNQ in stacked dimeric systems. Synthesis and crystal structure of [Ru(PPh3)2(TCNQ)]2(TCNQ = 7,7,8,8-tetracyanoquinodimethane)

Abstract

The reaction of [Ru(CO)2(PPh3)2(thf)2](BF4)2(thf = tetrahydrofuran) with PPh3 in CH2Cl2 and LiTCNQ in methanol leads to the formation of [Ru(PPh3)2(TCNQ)]; the crystal structure of this compound shows a tetrahedral environment of the ruthenium atom with the TCNQ molecule coordinated via N.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1396-1397

N-bonded TCNQ in stacked dimeric systems. Synthesis and crystal structure of [Ru(PPh3)2(TCNQ)]2(TCNQ = 7,7,8,8-tetracyanoquinodimethane)

L. Ballester, M. C. Barral, A. Gutiérrez, R. Jiménez-Aparicio, J. M. Martínez-Muyo, M. F. Perpiñan, M. A. Monge and C. Ruíz-Valero, J. Chem. Soc., Chem. Commun., 1991, 1396 DOI: 10.1039/C39910001396

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