The multidentate phosphido ligand [–P(CH2CH2PMe2)2] enables the isolation of new classes of zirconium phosphides; preliminary studies, including details of new complexes prepared and the crystal structure of a unique ZrIII binuclear complex with three phosphido ligands, each exhibiting different coordination behaviour, are reported.
P. G. Edwards, J. A. K. Howard, J. S. Parry and A-R. Al-Soudani, J. Chem. Soc., Chem. Commun., 1991, 1385 DOI: 10.1039/C39910001385
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