Issue 16, 1991

A model for the attack of a nucleophile on a nitrile group: the X-ray crystal structure of 2,2′-bipyridine-3,3′-dicarbonitrile

Abstract

From analysis of the geometry of the attractive intramolecular interactions between the pyridine N atoms and the nitrile C atoms in title compound 2 it is proposed that the most favoured direction of approach of a nucleophile to an sp C([triple bond, length half m-dash]N) makes an angle of at least 108° to the triple bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1135-1137

A model for the attack of a nucleophile on a nitrile group: the X-ray crystal structure of 2,2′-bipyridine-3,3′-dicarbonitrile

P. N. W. Baxter, J. A. Connor, D. C. Povey and J. D. Wallis, J. Chem. Soc., Chem. Commun., 1991, 1135 DOI: 10.1039/C39910001135

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements