Issue 16, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Transannularly bridged di-µ2-thiotetraborane(10). Dynamics, cis–trans-isomerism, reversible rearrangement: bis(diboranyl)‘butterfly’ structure

Herbert Binder,   Paraschos Melidis,   Serdar Söylemez  and  Gernot Heckmann  

Abstract

B4H10 reacts with bifunctional thiols to give transannularly bridged H2(µ2)2S2RBH(B2H5) which exist as cis–trans isomers; on cooling these compounds rearrange to cis–trans H2B(µ2)2S2RB3H6.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39910001091
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1091-1093

Permissions

Request permissions

Transannularly bridged di-µ2-thiotetraborane(10). Dynamics, cis–trans-isomerism, reversible rearrangement: bis(diboranyl)‘butterfly’ structure

H. Binder, P. Melidis, S. Söylemez and G. Heckmann, J. Chem. Soc., Chem. Commun., 1991, 1091 DOI: 10.1039/C39910001091

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements