Issue 8, 1991

Synthesis, binding properties and self-functionalization of a steroid-capped porphyrin

Abstract

A porphyrin capped with a steroidal superstructure bearing convergent hydroxy groups has been synthesized and shown to bind a variety of functionalized amines via a combination of metal–amine and hydrogen-bonding interactions; the metal–ligand interaction was used to catalyse and control selective acylation of a single hydroxy group in the cap.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 574-577

Synthesis, binding properties and self-functionalization of a steroid-capped porphyrin

R. P. Bonar-Law and J. K. M. Sanders, J. Chem. Soc., Chem. Commun., 1991, 574 DOI: 10.1039/C39910000574

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