The bimolecular reaction between RRSS-NiL2+(where L = 1,4,8,11-tetraazacyclotetradecane) and alkyl radicals (R˙) forms the organometallic species RNiL(H2O)2+, with rate constants that vary in the order Me ≫ primary ≫ secondary in aqueous perchloric acid at 25 °C, reflecting the decreasing strength of the nickel–carbon bond.
D. G. Kelley, J. H. Espenson and A. Bakac, J. Chem. Soc., Chem. Commun., 1991, 546 DOI: 10.1039/C39910000546
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