The reduction of cyclopropenes by metal hydrides shows significant parallels with their reduction by Klebsiella pneumoniae nitrogenase; intermediates isolated from the reduction of the isomeric allenes and acetylenes by [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] show novel features of much wider implication.
A. Hills, D. L. Hughes, M. Jimenez-Tenorio, G. J. Leigh, C. A. McGeary, A. T. Rowley, M. Bravo, C. E. McKenna and M. McKenna, J. Chem. Soc., Chem. Commun., 1991, 522 DOI: 10.1039/C39910000522
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