Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P and SO2 to give alkenes and in some cases products derived from benzylic radicals, the products are explained by a mechanism involving sulphonyl carbenes.
R. A. Aitken and M. J. Drysdale, J. Chem. Soc., Chem. Commun., 1991, 512 DOI: 10.1039/C39910000512
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