Chelate-stabilised halocarbon–platinum(II) complexes of the general type cis- and trans-[MePt(η2-Ph2PY)(η1-Ph2PY)][BF4] where Y = CH2CH2Cl, o-C6H4Cl or o-CH2C6H4X, X = Cl, Br or l, are reported and the relative trans-influence of the halocarbon donors is discussed; the X-ray crystal structures of [MePt(η2-Ph2PCH2CH2Cl)(η1-Ph2PCH2CH2Cl)][BF4] and [MePt{η2-Ph2P(o-C6H4Cl)}{η1-Ph2P(o-C6H4Cl)}][BF4] have been determined.
T. M. Gomes-Carneiro, R. D. Jackson, J. H. Downing, A. G. Orpen and P. G. Pringle, J. Chem. Soc., Chem. Commun., 1991, 317 DOI: 10.1039/C39910000317
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