Issue 5, 1991

Directive and shielding effects of the trimethylsilyl group. Unprecedented β-selectivity in the reaction of α,β-epoxyalkylsilanes with hindered α-sulphonyl anions

Abstract

Anions generated from hindered primary and secondary alkyl phenyl sulphones react with trimethylsilyloxirane to yield a mixture of products of addition in α- and β-positions or exclusively the product of addition in the β-position.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 297-298

Directive and shielding effects of the trimethylsilyl group. Unprecedented β-selectivity in the reaction of α,β-epoxyalkylsilanes with hindered α-sulphonyl anions

P. Jankowski, S. Marczak, M. Masnyk and J. Wicha, J. Chem. Soc., Chem. Commun., 1991, 297 DOI: 10.1039/C39910000297

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