Trimethylvinylsilane works as an effective chain transfer agent in the polymerisation of various substituted acetylenes by Mo and W catalysts, which enables the control of polymer molecular weight and verifies the metal-carbene mediated polymerisation mechanism.
T. Masuda, H. Kouzai and T. Higashimura, J. Chem. Soc., Chem. Commun., 1991, 252 DOI: 10.1039/C39910000252
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