The synthesis and structure of the first H2salen {2,2′-[1,2-ethanediylbis(nitrilomethylidyne)]diphenol} derived model for coenzyme B12 with an intramolecular carbon bridge between the ligand and cobalt are reported.
B. van Arkel, J. L. van der Baan, S. Balt, F. Bickelhaupt, M. W. G. de Bolster, I. E. Kingma, G. W. Klumpp, J. W. E. Moos and A. L. Spek, J. Chem. Soc., Chem. Commun., 1991, 225 DOI: 10.1039/C39910000225
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