Issue 1, 1991

(9,10-Dihydro-9,10-o-benzeno-2,6-anthrylene)di(phenylmethylene): a ground state quintet molecule

Abstract

The title molecule, which has two diphenylmethylene moieties in a rigid triptycene skeleton, is photochemically generated from the corresponding diazo compound at cryogenic temperature in an ESR cavity, and the ESR spectra is identified with a quintet ground state, with ZFS parameters, |D|/hc= 0.0665 and |E|/hc= 0.0043 cm–1, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 35-37

(9,10-Dihydro-9,10-o-benzeno-2,6-anthrylene)di(phenylmethylene): a ground state quintet molecule

H. Tukada and K. Mutai, J. Chem. Soc., Chem. Commun., 1991, 35 DOI: 10.1039/C39910000035

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