Some reactions of 2-azabicycio[2.2.1]hept-5-enes with diphenylketene: preparation of polysubstituted piperidin-2-ones
Abstract
The azanorbornenes (1) and (3) reacted with diphenylketene to give the 3-azabicyclo[4.3.0]-nonanones (7) and (5) respectively, while the spiro compound (9) afforded the cyclopentenol derivative (10) on reaction with the same ketene.