It has been established that the two minor products obtained from the reaction of 6-cyano-tricyclo[5.5.0.0]dodeca-3,6,9,12-tetraene (3) with DDQ are 6-cyano-Dewar aceheptylene (5) and 5-cyanobenz[a]azulene (6), the formation of which show a new mode for the reaction of a substituted 8-cyanoheptafulvene with DDQ.
S. Wakabayashi, Y. Sugihara, Y. Hayakawa and I. Murata, J. Chem. Soc., Perkin Trans. 1, 1990, 1489 DOI: 10.1039/P19900001489
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