The Pitzer method with higher-order limiting laws is examined and discussed. The reason for its inability to produce convincing results is identified. Improvements in terms of theory and accuracy are proposed. The experimental activity coefficients for the mixture HCl–KCl in water at 25 °C were used for testing. The results are analysed and discussed.
T. Lim, J. Chem. Soc., Faraday Trans., 1990, 86, 3897 DOI: 10.1039/FT9908603897
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