The hydrogen-abstraction reaction of 9,10-anthraquinone (AQ) from xanthene has been investigated by the CIDEP and CIDNP methods. The CIDNP spectrum is explained by a radical-pair mechanism, but a triplet mechanism contributes to the CIDEP spectrum. The products of AQ with xanthene are discussed.
M. Terazima, K. Maeda, M. Sugawara, S. Takahashi and T. Azumi, J. Chem. Soc., Faraday Trans., 1990, 86, 253 DOI: 10.1039/FT9908600253
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