Issue 1, 1990

Reaction of ground-state aluminium atoms with diethyl ether. Electron spin resonance evidence for insertion into the CH and CC bonds

Abstract

Ground-state Al atoms react with diethyl ether on solid hydrocarbon surfaces at 77 K in a rotating cryostat to give several mononuclear aluminium(o) compounds. The magnetic parameters of two of these compounds are consistent with the formation of CH3CHAlH(OCH2CH3) and/or CH3CH2OCH2CH2AlH and CH3AlCH2OCH2CH3 produced by insertion of the Al atom into the CH and CC bonds of the ether. A third species could be CH3CH2OAlCH2CH3, given by insertion into the CO bond, but this assignment is somewhat tentative.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans., 1990,86, 219-220

Reaction of ground-state aluminium atoms with diethyl ether. Electron spin resonance evidence for insertion into the CH and CC bonds

J. A. Howard, H. A. Joly and B. Mile, J. Chem. Soc., Faraday Trans., 1990, 86, 219 DOI: 10.1039/FT9908600219

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