Some binuclear iron(III) complexes with µ-phenoxo and µ-alkoxo bridges have been found to show high ability for the peroxidation of linolenic and linolic acid under aerobic conditions. The possibility of dioxygen activation in a substrate–metal complex–O2 intermediate is discussed.
Y. Nishida and K. Yamada, J. Chem. Soc., Dalton Trans., 1990, 3639 DOI: 10.1039/DT9900003639
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