Issue 24, 1990

Novel photochemical synthesis of a model spiro compound related to fredericamycin-A

Abstract

Photolysis of the enones 4ac leads to regioselective hydrogen abstraction and subsequent cyclization to furnish the spiro compounds 5ad, which on further elaboration provide the spiro dione 6, a model for the antitumour antibiotic, fredericamycin-A 1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1791-1792

Novel photochemical synthesis of a model spiro compound related to fredericamycin-A

B. Pandey, U. R. Khire and N. R. Ayyangar, J. Chem. Soc., Chem. Commun., 1990, 1791 DOI: 10.1039/C39900001791

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