Oxygen atom transfer to manganese(II) tetraphenylporphyrin (tpp) and iron(II) tetramesitylporphyrin (tmp) is readily effected at < –10 °C with dimethyldioxirane in anhydrous acetone to afford the labile oxometal species O![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
MnIV(tpp) and OFeIV(tmp) in quantitative yields.
S. Wolowiec and J. K. Kochi, J. Chem. Soc., Chem. Commun., 1990, 1782 DOI: 10.1039/C39900001782
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...